A process for the direct recovery of tin values, as organo hydrocarbyl tin compounds, from reduced but unrefined tin ores and ore slags is described, wherein the ore or slag is reacted directly with a hydrocarbyl halide to form an organo hydrocarbyl tin compound which can then easily be separated from the tin-depleted ore or slag residue.

Introduction of extraction of tin from its ore. Rock Tin ore is one of the metals that mankind first discovered. In the early days, our ancestors' innovative extraction of tin from its ore, used tin, copper and lead to produce bronzes.Tin and tin alloys have been …

Peroxide. Thei experimentr includes d a Titanium Tin ore. This method as applied t Cassiterito hae s bee highln y 13 recommended by Gray. In general eve, n where the sodiu hydroxidm e fusion is successful, the peroxide ha bees founn d to produce a surer, safer, and more complet e …

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9. The process of claim 7 wherein the reduced, unrefined tin ore or tin slag is heated with the hydrocarbyl halide and `onium` compound at a temperature between 100° and 200° C. under reflux. 10. The process of claim 9 wherein the organo hydrocarbyl tin compounds formed are separated from the tin-depleted ore residues by solvent extraction. 11.